• 文献标题:   Spin glass like transition and the exchange bias effect in Co3O4 nanoparticles anchored onto graphene sheets
  • 文献类型:   Article
  • 作  者:   SARKAR S, MONDAL A, GIRI N, RAY R
  • 作者关键词:  
  • 出版物名称:   PHYSICAL CHEMISTRY CHEMICAL PHYSICS
  • ISSN:   1463-9076 EI 1463-9084
  • 通讯作者地址:   Jadavpur Univ
  • 被引频次:   7
  • DOI:   10.1039/c8cp06659k
  • 出版年:   2019

▎ 摘  要

We have synthesized Co3O4 nanoparticles having 40 nm average size, which are anchored on reduced graphene oxide. X-ray diffraction, FESEM, TEM and Raman spectroscopy are performed for the characterization. The temperature dependence of field cooled (FC) and zero field cooled (ZFC) magnetization curves exhibits antiferromagnetic (AFM) transition around approximate to 30 K, as observed for bulk Co3O4. The exchange bias effect is observed below approximate to 30 K. A significant change in the exchange bias effect is noted around approximate to 8 K, which is close to a spin-glass-like transition. The spin-glass-like phase has been confirmed by the memory effects observed by different experimental protocols. The possible origin of exchange bias is discussed in the manuscript.