▎ 摘　　要

Carbon microtube/graphene (CMT/GR) hybrid structures were prepared from a natural biomass material (absorbent cotton) by the carbonization and continuous chemical vapour deposition (CVD) of graphene at 1200 degrees C. The graphene nanosheets deposited by CVD had a few-layer structure and were uniformly coated on the surface of the CMTs. The CMT/GR composite had a hollow tubular structure, a specific surface area of about 312 m(2) g(-1) and was highly hydrophobic (contact angle about 128 degrees). The CMT/GR hybrid acted as a thermally conductive supporting framework and organic octadecanoic acid (OA) was easily impregnated into the CMT/GR structure by capillary forces. The CMT/GR/OA composite had a thermal conductivity of about 0.69 W m(-1) K-1 at a CMT/GR loading fraction of about 10 wt%, which is about 4.3 times larger than that of OA (about 0.16 W m(-1) K-1). The CMT/GR/OA composite had a high heat storage capacity of about 174 J g(-1), very close to the value of OA (about 186 J g(-1)) and showed good thermal reliability even after 500 melting/freezing cycles. This method produces novel shape-stabilized phase change materials for use in thermal energy storage applications and has given new insights into the design and preparation of CMT/GR hybrid structures from natural resources.