• 文献标题:   Graphene: an exotic condensed matter and its impact on technology
  • 文献类型:   Article
  • 作  者:   SHARMA BK
  • 作者关键词:   hall effect, nanoelectronic, selfassembled monolayer
  • 出版物名称:   EMERGING MATERIALS RESEARCH
  • ISSN:   2046-0147 EI 2046-0155
  • 通讯作者地址:   Natl Inst Technol Patna
  • 被引频次:   0
  • DOI:   10.1680/jemmr.16.00147
  • 出版年:   2020

▎ 摘  要

Graphene is a (2 + 1)-dimensional quantum electrodynamic system. The carriers have a vanishing mass and a relativistic velocity of 10(6) m/s, obeying charge-conjugate parity time symmetry. Graphene exhibits the Klein paradox, due to which, through spatial confinement, a bandgap can be opened in zigzag graphene nanoribbons for logic applications. The high Debye temperature of 2800 K ensures that phonons are frozen out and lattice scattering is suppressed at 300 K. The perfect crystallinity ensures that defect/impurity scattering is suppressed. The two together give very high electrical conductivity and electric mobility. This permits a current density of 10(8) A/cm(2), about 100 times greater than that in copper. Single-layer graphene has a thermal conductivity of 3000-5000 (W/m)/K at 300 K, but graphite has K = 2000 (W/m)/K. This may open up few-layer graphene applications in thermal management of nanoelectronics. The half-integer quantum Hall effect and non-zero Berry phase have been verified in the laboratory. These magneto-transport properties are a result of the exceptional topology of the graphene band structure. Ballistic transport observable up to 300 K makes graphene an ideal replacement for silicon (Si) electronics. The optical response of graphene is determined by the fine-structure constant over a wide band of the visible spectrum, and hence, it is ideal for high-speed optical modulators. This paper describes a commercially significant process for synthesizing large-area fold-free and defect-free graphene.