• 文献标题:   Binder-free graphene and manganese oxide coated carbon felt anode for high-performance microbial fuel cell
  • 文献类型:   Article
  • 作  者:   ZHANG CY, LIANG P, YANG XF, JIANG Y, BIAN YH, CHEN CM, ZHANG XY, HUANG X
  • 作者关键词:   reduced graphene oxide, manganese oxide, carbon felt, extracellular electron transfer, microbial fuel cell
  • 出版物名称:   BIOSENSORS BIOELECTRONICS
  • ISSN:   0956-5663 EI 1873-4235
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   48
  • DOI:   10.1016/j.bios.2016.02.051
  • 出版年:   2016

▎ 摘  要

A novel anode was developed by coating reduced graphene oxide (rGO) and manganese oxide (MnO2) composite on the carbon felt (CF) surface. With a large surface area and excellent electrical conductivity, this binder-free anode was found to effectively enhance the enrichment and growth of electrochemically active bacteria and facilitate the extracellular electron transfer from the bacteria to the anode. A microbial fuel cell (MFC) equipped with the rGO/MnO2/CF anode delivered a maximum power density of 2065 mW m(-2), 154% higher than that with a bare CF anode. The internal resistance of the MFC with this novel anode was 79 Omega, 66% lower than the regular one's (234 Omega). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) analyses affirmed that the rGO/MnO2 composite significantly increased the anodic reaction rates and facilitated the electron transfer from the bacteria to the anode. The findings from this study suggest that the rGO/MnO2/CF anode, fabricated via a simple dip-coating and electro-deposition process, could be a promising anode material for high-performance MFC applications. (C) 2016 Elsevier B.V. All rights reserved.