• 文献标题:   Lithium Titanate Tailored by Cathodically Induced Graphene for an Ultrafast Lithium Ion Battery
  • 文献类型:   Article
  • 作  者:   YANG YC, QIAO BH, YANG XM, FANG LB, PAN CC, SONG WX, HOU HS, JI XB
  • 作者关键词:  
  • 出版物名称:   ADVANCED FUNCTIONAL MATERIALS
  • ISSN:   1616-301X EI 1616-3028
  • 通讯作者地址:   Cent S Univ
  • 被引频次:   106
  • DOI:   10.1002/adfm.201304263
  • 出版年:   2014

▎ 摘  要

Nonoxidative cathodically induced graphene (CIG) here incorporates conductive agents for Li4Ti5O12 (LTO) anode materials. The tailored LTO/CIG composite is fabricated by controlled hydrolysis of tetrabutyl titanate in the presence of nonoxidative defect-free cathodically induced graphene (CIG) and oxalic acid in a mixed solvent of ethanol and water, followed by hydrothermal reaction and a calcination treatment. Due to the introduction of defect-free graphene, the resulting LTO/CIG composite shows an excellent electrical conductivity (1.2 x 10(-4) S cm(-1)) and Li+ diffusion coefficient (1.61 x 10(-12) cm(2) s(-1)). As a result, the tuned LTO/CIG composite exhibits outstanding electrochemical performance, including excellent cycling stability (the capacity retention ratios after 500 cycles at 0.5 C is 96.2%) and a remarkable rate capability (162 mAh g(-1) at 10 C, 126 mAh g(-1) at 100 C). A specific energy of 272 Wh kg(-1) at power of 136 W kg(-1) is observed when cycling against Li-foil. Even during 36 s of charge/discharge, the specific energy of LTO/CIG composite remains at 166 Wh kg(-1)