• 文献标题:   Construction of a highly sensitive non-enzymatic nitrite sensor using electrochemically reduced holey graphene
  • 文献类型:   Article
  • 作  者:   ZHANG J, ZHANG Y, ZHOU J, WANG L
  • 作者关键词:   electrochemically reduced holey graphene, electron transfer, mass transport, edge plane, nitrite sensor
  • 出版物名称:   ANALYTICA CHIMICA ACTA
  • ISSN:   0003-2670 EI 1873-4324
  • 通讯作者地址:   Shanghai Univ Engn Sci
  • 被引频次:   8
  • DOI:   10.1016/j.aca.2018.08.045
  • 出版年:   2018

▎ 摘  要

An electrochemical nitrite sensor based on electrochemically reduced holey graphene (ERHG) was fabricated in this study. An abundant of nanopores were observed on the basal plane of the ERHG, and, with the aid of in-plane pores, many more exposed edge plane and a high density of defects were found. Both these phenomena can significantly improve the electron transfer and mass transport of electrodes. The ERHG-modified electrode showed superior electrocatalytic activity toward nitrites with a wide linear range, high sensitivity, and a low detection limit. Furthermore, the ERHG nitrite sensor showed excellent anti-interference ability and reproducibility, long-term stability, and fulfilled requirements for application to real samples. (C) 2018 Elsevier B.V. All rights reserved.