• 文献标题:   Synthesis and characterization of CeO2-graphene composite
  • 文献类型:   Article
  • 作  者:   DA SILVA MFP, DA COSTA HCDF, TRIBONI ER, POLITI MJ, ISOLANI PC
  • 作者关键词:   graphene, ceo2, composite, grapheneceo2, hybrid material, thermal analysi
  • 出版物名称:   JOURNAL OF THERMAL ANALYSIS CALORIMETRY
  • ISSN:   1388-6150 EI 1588-2926
  • 通讯作者地址:   Univ Sao Paulo
  • 被引频次:   17
  • DOI:   10.1007/s10973-011-1924-8
  • 出版年:   2012

▎ 摘  要

The synthesis and characterization of graphite oxide (GO), graphene (GS), and the composites: GS-CeO2 and GO-CeO2 are reported. This synthesis was carried out by mixing aqueous solutions of CeCl3 center dot 7H(2)O and GO, which yields the oxidized composite GO-CeO2. GO-CeO2 was hydrothermally reduced with ethylene glycol, at 120 A degrees C, yielding the reduced composite GS-CeO2. GO, GS ,and the composites with CeO2 were characterized by CHN, TG/DTG, BET, XRD, SEM microscopy, FTIR, and Raman spectroscopy. The estimation of crystallite size of CeO2 anchored on GO and on GS by Raman, XRD, and SEM agreed very well showing diameters about 5 nm. The role of particles of CeO2 coating carbon sheets of GO and GS was discussed.