• 文献标题:   Tunability by alkali metal cations of photoinduced charge separation in azacrown functionalized graphene
  • 文献类型:   Article
  • 作  者:   BALLESTEROSGARRIDO R, DE MIGUEL M, DOMENECHCARBO A, ALVARO M, GARCIA H
  • 作者关键词:  
  • 出版物名称:   CHEMICAL COMMUNICATIONS
  • ISSN:   1359-7345 EI 1364-548X
  • 通讯作者地址:   Univ Politecn Valencia
  • 被引频次:   14
  • DOI:   10.1039/c3cc39145k
  • 出版年:   2013

▎ 摘  要

A modified graphene oxide containing aza-9-crown-3 ether units covalently anchored has been prepared; aqueous suspensions of this material in the presence of Li+, Na+ and K+ cations exhibit enhanced electrochemical response, enhanced photoinduced charge separation and longer lifetimes, facts that can be attributed to stabilization of electrons on graphene oxide by the nearby alkali metal cation-azacrown complexes.