• 文献标题:   Phosphorus-Doped Exfoliated Graphene for Supercapacitor Electrodes
  • 文献类型:   Article
  • 作  者:   KARTHIKA P, RAJALAKSHMI N, DHATHATHREYAN KS
  • 作者关键词:   graphene, supercapacitor, phosphoru, hummer s method, alkaline reduction
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   IITM
  • 被引频次:   52
  • DOI:   10.1166/jnn.2013.7112
  • 出版年:   2013

▎ 摘  要

Graphene, a single atom thick carbon material with high surface area and electrical conductivity provides an ideal platform for designing high performance electrochemical devices. This paper reports the synthesis of phosphorous doped graphene from reduced graphene sheets, its characterization by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and Raman spectroscopy and its use for supercapacitor applications. The specific capacitance was found to be 367 Fg(-1) from electrochemical measurements. These samples show a high power density of 9 kW kg(-1) and energy density of 59 Wh kg(-1) in an aqueous electrolyte solution, which is much higher than other graphene-based supercapacitors. The phosphorus-doped graphene showed a high potential for use in low cost energy storage devices.