• 文献标题:   Large bandgap of pressurized trilayer graphene
  • 文献类型:   Article
  • 作  者:   KE F, CHEN YB, YIN KT, YAN JJ, ZHANG HZ, LIU ZX, TSE JS, WU JQ, MAO HK, CHEN B
  • 作者关键词:   graphene, twodimensional material, high pressure, electrical transport, bandgap opening
  • 出版物名称:   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
  • ISSN:   0027-8424
  • 通讯作者地址:   Ctr High Pressure Sci Technol Adv Res
  • 被引频次:   12
  • DOI:   10.1073/pnas.1820890116
  • 出版年:   2019

▎ 摘  要

Graphene-based nanodevices have been developed rapidly and are now considered a strong contender for postsilicon electronics. However, one challenge facing graphene-based transistors is opening a sizable bandgap in graphene. The largest bandgap achieved so far is several hundred meV in bilayer graphene, but this value is still far below the threshold for practical applications. Through in situ electrical measurements, we observed a semiconducting character in compressed trilayer graphene by tuning the interlayer interaction with pressure. The optical absorption measurements demonstrate that an intrinsic bandgap of 2.5 +/- 0.3 eV could be achieved in such a semiconducting state, and once opened could be preserved to a few GPa. The realization of wide bandgap in compressed trilayer graphene offers opportunities in carbon-based electronic devices.