• 文献标题:   Reduced graphene oxide/titanium carbide MXene nanocomposite-modified electrode for electrochemical hemoglobin biosensor
  • 文献类型:   Article
  • 作  者:   SUN YX, WANG BL, DENG Y, CHENG H, LI XQ, YAN LJ, LI GJ, SUN W
  • 作者关键词:   direct electrochemistry, electrocatalysi, electrochemical biosensor, hemoglobin, reduced graphene oxide, ti3c2tx
  • 出版物名称:   JOURNAL OF THE CHINESE CHEMICAL SOCIETY
  • ISSN:   0009-4536 EI 2192-6549
  • 通讯作者地址:  
  • 被引频次:   5
  • DOI:   10.1002/jccs.202100229 EA NOV 2021
  • 出版年:   2021

▎ 摘  要

In this work, reduced graphene oxide (rGO) and titanium carbide (Ti3C2Tx) nanocomposite was prepared by the self-assembly method and used for electrode modification. The rGO-Ti3C2Tx nanocomposite was examined by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. Then, an electrochemical hemoglobin (Hb) biosensor was prepared on the nanocomposite-modified electrode and used for the determination of trichloroacetic acid (TCA) and hydrogen peroxide (H2O2). Direct electrochemistry of Hb on the modified electrode was examined with the calculations of the electron transfer number, electron transfer coefficient, and the reaction rate constant. The presence of the rGO-Ti3C2Tx nanocomposite on the electrode can improve the effective surface area and biocompatibility of the electrode interface, obtaining a higher electron transfer rate. Furthermore, this electrochemical Hb biosensor exhibited excellent stability, reproducibility, and repeatability in TCA and H2O2 analyses.