• 文献标题:   Atomic intercalation to measure adhesion of graphene on graphite
  • 文献类型:   Article
  • 作  者:   WANG J, SORESCU DC, JEON S, BELIANINOV A, KALININ SV, BADDORF AP, MAKSYMOVYCH P
  • 作者关键词:  
  • 出版物名称:   NATURE COMMUNICATIONS
  • ISSN:   2041-1723
  • 通讯作者地址:   Oak Ridge Natl Lab
  • 被引频次:   11
  • DOI:   10.1038/ncomms13263
  • 出版年:   2016

▎ 摘  要

The interest in mechanical properties of two-dimensional materials has emerged in light of new device concepts taking advantage of flexing, adhesion and friction. Here we demonstrate an effective method to measure adhesion of graphene atop highly ordered pyrolytic graphite, utilizing atomic-scale 'blisters' created in the top layer by neon atom intercalates. Detailed analysis of scanning tunnelling microscopy images is used to reconstruct atomic positions and the strain map within the deformed graphene layer, and demonstrate the tip-induced subsurface translation of neon atoms. We invoke an analytical model, originally devised for graphene macroscopic deformations, to determine the graphite adhesion energy of 0.221 +/- 0.011 J m(-2). This value is in excellent agreement with reported macroscopic values and our atomistic simulations. This implies mechanical properties of graphene scale down to a few-nanometre length. The simplicity of our method provides a unique opportunity to investigate the local variability of nanomechanical properties in layered materials.