• 文献标题:   Symmetry Breaking of Graphene Monolayers by Molecular Decoration
  • 文献类型:   Article
  • 作  者:   DONG XC, SHI YM, ZHAO Y, CHEN DM, YE J, YAO YG, GAO F, NI ZH, YU T, SHEN ZX, HUANG YX, CHEN P, LI LJ
  • 作者关键词:  
  • 出版物名称:   PHYSICAL REVIEW LETTERS
  • ISSN:   0031-9007 EI 1079-7114
  • 通讯作者地址:   Nanyang Technol Univ
  • 被引频次:   185
  • DOI:   10.1103/PhysRevLett.102.135501
  • 出版年:   2009

▎ 摘  要

Aromatic molecules can effectively exfoliate graphite into graphene monolayers, and the resulting graphene monolayers sandwiched by the aromatic molecules exhibit a pronounced Raman G-band splitting, similar to that observed in single-walled carbon nanotubes. Raman measurements and calculations based on the force-constant model demonstrate that the absorbed aromatic molecules are responsible for the G-band splitting by removing the energy degeneracy of in-plane longitudinal and transverse optical phonons at the Gamma point.