• 文献标题:   Modification of Chemically Exfoliated Graphene to Produce Efficient Piezoresistive Polystyrene-Graphene Composites
  • 文献类型:   Article
  • 作  者:   NASIRPOURI F, POURMAHMOUDI H, ABBASI F, LITTLEJOHN S, CHAUHAN AS, NOGARET A
  • 作者关键词:   graphene, chemical exfoliation, polystyrene, raman spectroscopy
  • 出版物名称:   JOURNAL OF ELECTRONIC MATERIALS
  • ISSN:   0361-5235 EI 1543-186X
  • 通讯作者地址:   Sahand Univ Technol
  • 被引频次:   9
  • DOI:   10.1007/s11664-015-3799-0
  • 出版年:   2015

▎ 摘  要

We report the chemical exfoliation of grapheneoxide from graphite and its subsequent reduction to graphene nanosheets (GN) to obtain highly conducting composites of graphene sheets in a polymer matrix. The effect of using graphite nanoparticles or flakes as precursors, and different drying methods, was investigated to obtain multilayer graphene sheets of atomically controlled thickness, which was essential to optimizing their dispersion in a polystyrene (PS) polymer matrix. In situ emulsion polymerization of the styrene monomer in the presence of GN was performed to obtain thin composite films with highly uniform dispersion and fewer graphene layers when GN were obtained from graphite flakes then freeze drying. The highest electrical conductivity of PS-GN composites was similar to 0.01 S/m for a graphene filling fraction of 2%. The piezoresistance of the PS-GN composites was evaluated and used in pressure sensor arrays with pressure field imaging capability.