• 文献标题:   Fabrication of graphene-based 3D structures by stereolithography
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   KORHONEN H, SINH LH, LUONG ND, LEHTINEN P, VERHO T, PARTANEN J, SEPPALA J
  • 作者关键词:   graphene, printing, pyrolysi, sheet resistance, stereolithography, threedimensional structure
  • 出版物名称:   PHYSICA STATUS SOLIDI AAPPLICATIONS MATERIALS SCIENCE
  • ISSN:   1862-6300 EI 1862-6319
  • 通讯作者地址:   Aalto Univ
  • 被引频次:   14
  • DOI:   10.1002/pssa.201532761
  • 出版年:   2016

▎ 摘  要

Stereolithographic fabrication of graphene-based 3D constructs was demonstrated. The photocrosslinkable resin/graphene oxide mixtures were fabricated to samples that closely followed the structure of the designed 3D model. After 3D printings, the graphene oxide/polymer composites were pyrolyzed to reduce graphene oxide to electrically conductive graphene and to decompose the polymer, resulting in 3D structures consisting entirely of graphene. The method presented in this paper proved to be successful for producing designed 3D structures but further optimization is needed for practical applications due to high shrinking and brittleness of the pyrolyzed 3D constructs. By pyrolyzing the polymer component only partly, electrical conductivities in the range of semiconductors were achieved.