• 文献标题:   In Situ Raman Studies of Electrically Reduced Graphene Oxide and Its Field-Emission Properties
  • 文献类型:   Article
  • 作  者:   SAHOO S, KHURANA G, BARIK SK, DUSSAN S, BARRIONUEVO D, KATIYAR RS
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447 EI 1932-7455
  • 通讯作者地址:   Univ Puerto Rico
  • 被引频次:   26
  • DOI:   10.1021/jp400573w
  • 出版年:   2013

▎ 摘  要

Electric-field-dependent in situ Raman studies have been carried out on chemically prepared graphene oxide The Raman spectra show significant changes with increase in the applied electric field; in particular, the intensity of the G peak decreases with electric field. This behavior is typical for chemically or thermally reduced graphene oxide. To understand the nature of reduction, we compared the temperature-dependent and electric-field-dependent Raman spectra of graphene oxide and found that the evolutions of Raman spectra are not in agreement with each other, except the intensity of the G peak that decreases in both cases. The D peak broadens significantly with increase in temperature, whereas it sharpens in the case of applied electric field. The electron-field-emission properties of the electrically reduced graphene oxide were also carried out, and the turn-on field was found to be 9.1 V/mu m.