▎ 摘　　要

Functionalization of graphene-based materials using chemical moieties not only modify the electronic structure of the underlying graphene but also enable in limited enhancement of targeted properties. Surface modification of graphene-based materials using other nanostructures enhances the effective properties by minimally modifying the properties of pristine graphene backbone. In this pursuit, we have synthesized bio-inspired hierarchical nanostructures based on Ni-Co layered double hydroxide on reduced graphene oxide core-shells using template based wet chemical approach. The material synthesized have been characterized structurally and electrochemically. The fabricated dendritic morphology of the composite delivers a high specific capacity of 1056 Cg(-1). A cost effective solid state hybrid supercapacitor device was also fabricated using the synthesized electrode material which shows excellent performance with high energy density and fast charging capability.