• 文献标题:   Photoinduced Charge Separation on the Microsecond Timescale in Graphene Oxide and Reduced Graphene Oxide Suspensions
  • 文献类型:   Article
  • 作  者:   BALDOVI HG, ALVARO M, FERRER B, GARCIA H
  • 作者关键词:   charge separation, graphene, photochemistry, reduced graphene oxide, timeresolved spectroscopy
  • 出版物名称:   CHEMPHYSCHEM
  • ISSN:   1439-4235 EI 1439-7641
  • 通讯作者地址:   CSIC UPV
  • 被引频次:   6
  • DOI:   10.1002/cphc.201500986
  • 出版年:   2016

▎ 摘  要

Transient absorption spectroscopy of graphene oxide (GO) and reduced graphene oxide (rGO) suspensions provides evidence for the photochemical generation of a charge-separated state on the microsecond timescale upon laser excitation. The lifetime and quantum yield of charge separation in suspended rGO were found to be higher than for GO. This could be advantageous for optoelectronic and photocatalytic applications, where graphene-based materials act as charge (electron) carriers. The electron-transfer quenching of the rGO charge-separated state by different amines is more efficient when the amine is a better electron donor and more easily oxidized.