• 文献标题:   Synthesis of Few-Layer Reduced Graphene Oxide for Lithium-Ion Battery Electrode Materials
  • 文献类型:   Article
  • 作  者:   LI JH, LI LF, ZHANG BW, YU M, MA HJ, ZHANG JY, ZHANG C, LI JY
  • 作者关键词:  
  • 出版物名称:   INDUSTRIAL ENGINEERING CHEMISTRY RESEARCH
  • ISSN:   0888-5885
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   17
  • DOI:   10.1021/ie5018282
  • 出版年:   2014

▎ 摘  要

We report here a rapid and cost-effective approach to synthesize few-layer reduced graphene oxide (FL-RGO) in graphene oxide solution using EDA as a reducing agent and a cross-linker, and where the resulting FL-RGO was characterized by means of AFM, TEM, XPS, UV-vis, and XRD spectroscopies. A mechanism for forming the FL-RGO via removal of epoxide and hydroxyl groups from GO and stitching of the GO sheets by EDA in a water solution was proposed. FL-RGO was also tested as the electrolyte for a Li+-ion battery and showed advantages with a 346 mAh g(-1) capacity at a charge/discharge current density of 1C even after 60 cycles, which is comparable to the theoretical capacity of the graphite (372 inAh g(-1)).