• 文献标题:   Graphene oxide/poly(2-methylaniline) composite particle suspension and its electro-response
  • 文献类型:   Article
  • 作  者:   SIM B, ZHANG WL, CHOI HJ
  • 作者关键词:   composite material, electronic material, polymer, electrical propertie
  • 出版物名称:   MATERIALS CHEMISTRY PHYSICS
  • ISSN:   0254-0584 EI 1879-3312
  • 通讯作者地址:   Inha Univ
  • 被引频次:   13
  • DOI:   10.1016/j.matchemphys.2015.01.039
  • 出版年:   2015

▎ 摘  要

Graphene oxide (GO)/poly(2-methylaniline) (P2MAN) composite particles were prepared by chemical oxidation polymerization and adopted as an electrorheological (ER) material. Because of its electrical conductivity originating from both semi-conducting P2MAN and GO, it could be tuned finely using P2MAN for ER applications. The morphology and chemical structure of the composite were examined by scanning electron microscopy, Fourier transform infrared spectroscopy and X-ray diffraction. The ER properties of the GO/P2MAN composite particles dispersed in silicone oil were examined with and without an applied electric field. The fibrillation phenomenon of this GO/P2MAN-based electro-responsive fluid was also observed by optical microscopy under an electric field. The flow curves and dynamic modulus of the GO/P2MAN suspension were measured by rotational rheometry under a range of electric field strengths, exhibiting typical ER characteristics and a slope of the dynamic yield stress of 1.5. GO appeared to improve the compatibility of the composite particles within the medium, which resulted in improved sedimentation stability compared to that of the P2MAN-based ER fluid. (C) 2015 Elsevier B.V. All rights reserved.