• 文献标题:   S, N co-doped graphene quantum dots decorated CdSe for enhanced photoelectric properties
  • 文献类型:   Article
  • 作  者:   OUYANG Z, LEI Y, LUO LQ, JIANG ZC, HU JX, LIN YY
  • 作者关键词:   codoped, graphene quantum dot, cdse, photoelectric propertie, doping ratio
  • 出版物名称:   NANOTECHNOLOGY
  • ISSN:   0957-4484 EI 1361-6528
  • 通讯作者地址:   Wuhan Univ Technol
  • 被引频次:   1
  • DOI:   10.1088/1361-6528/ab589c
  • 出版年:   2020

▎ 摘  要

Cadmium selenide and S, N co-doped graphene quantum dots (CdSe/S, N-GQDs) nanocomposites were synthesized via a solvothermal method. The results show that S, N-GQDs have a grain size of around 5 nm and an average height of 0.5 nm, which contains only 1-2 layers of graphene sheets. The CdSe/S, N-GQDs composites exhibit distinct lattice fringes with a layer spacing of 0.24 and 0.35 nm, corresponding to (1120) and (111) crystal planes of S, N-GQDs and the cubic CdSe, respectively. The photoelectric properties of CdSe/S, N-GQDs were evaluated under ultraviolet light (365 nm) irradiation. Compared with CdSe and CdSe/GQDs, CdSe/S, N-GQDs composites have the largest photocurrent density of 4.286 x 10(-5) A cm(-2), which is about 10.5 times and 7.5 times as high as that of CdSe and CdSe/GQDs, respectively. The increase in photocurrent density of CdSe/S, N-GQDs can be attributed to the incorporation of S and N to promote separation of photogenerated carriers. Moreover, S, N-GQDs are nano-fragments of graphene, which can provide a larger specific surface area and greatly increase the contact surface with CdSe. In addition, the photoelectric properties of CdSe/S, N-GQDs composites can be adjusted by varying the doping ratio. When the doping ratio is 1:1, CdSe/S, N-GQDs have the best photoelectric performance.