• 文献标题:   Nanocomposites of zeolitic imidazolate frameworks on graphene oxide for pseudocapacitor applications
  • 文献类型:   Article
  • 作  者:   ZHANG W, TAN YY, GAO YL, WU JX, HU JB, STEIN A, TANG BHJ
  • 作者关键词:   pseudocapacitor, electrode, zeolitic imidazolate framework zif, metalorganic framework mof, graphene oxide
  • 出版物名称:   JOURNAL OF APPLIED ELECTROCHEMISTRY
  • ISSN:   0021-891X EI 1572-8838
  • 通讯作者地址:   Shanghai Univ Engn Sci
  • 被引频次:   23
  • DOI:   10.1007/s10800-016-0921-9
  • 出版年:   2016

▎ 摘  要

Nanocomposites consisting of zeolitic imidazolate framework nanocrystals on graphene oxide (ZIF/GO) are prepared by a facile ultrasonic method under ambient conditions. Brunauer-Emmett-Teller specific surface area measurements show that surface areas of the graphene composites are greatly increased by the addition of the ZIF component. Electrochemical properties of the nanocrystal-modified electrodes are measured by cyclic voltammetry, galvanostatic charge/discharge and electrochemical impedance spectroscopy in 6 M KOH electrolyte. Nanocomposites of ZIF-8/GO and ZIF-67/GO exhibit high specific capacitance values up to 400 and 252 F g(-1), respectively, much higher than that of each ZIF by itself. In addition to the good pseudocapacitive behavior, they exhibit excellent cycling performance, indicating that the ZIF nanoparticles grown on the surface of GO are beneficial to improving electrochemical properties. The ZIF nanocrystals grown on the surface of GO were beneficial to improving the electrochemical performance of the electrode materials.