• 文献标题:   Graphene-TiO2 for scattering layer in photoanodes of dye-sensitized solar cell
  • 文献类型:   Article
  • 作  者:   MIN KW, CHAO SM, YU MT, HO CT, CHEN PR, WU TL
  • 作者关键词:   graphene, tio2, dssc
  • 出版物名称:   MODERN PHYSICS LETTERS B
  • ISSN:   0217-9849 EI 1793-6640
  • 通讯作者地址:  
  • 被引频次:   4
  • DOI:   10.1142/S0217984921410050
  • 出版年:   2021

▎ 摘  要

The scattering layer in the TiO2 photoanode (PAs) of dye-sensitized solar cells (DSSCs) is doped with single-layer graphene (G), and DSSC is prepared by doctor blade coating method. A small amount of graphene (0.0016 wt.%) in a graphene aqueous solution (G-AS) and a G-TiO2 paste was prepared to make 2-20 wt.% of G-AS in the deionized water (DIW). The UV-Vis measurement results show that the TiO2 scattering layers doped with graphene effectively improve the visible light absorption intensity of DSSC PAs and increase the current density (Jsc) from 13.84 mA/cm(2) to 16.20 mA/cm(2). The Electrochemical Impedance Spectroscopy (EIS) measurement showed that the internal structural impedance Rk (Omega) decreased from 12.086 (Omega) (without graphene doping) to 9.875 (Omega) at 5 wt.% of the graphene doping. The photoelectric conversion efficiency (PCE) increased from 6.56% of the original un-doped graphene to the maximum PCE value of 7.57% at 5 wt.%. The results show that the best PCE is obtained when the concentration of G-AS is 5 wt.%.