• 文献标题:   A porous graphene/carbon nanowire hybrid with embedded SnO2 nanocrystals for high performance lithium ion storage
  • 文献类型:   Article
  • 作  者:   TANG JJ, YANG J, ZHOU XY, YAO HM, ZHOU LM
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Hong Kong Polytech Univ
  • 被引频次:   31
  • DOI:   10.1039/c5ta06859b
  • 出版年:   2015

▎ 摘  要

A high-yield porous graphene/carbon nanowire (PG/CNW) hybrid is synthesized via in situ chemical oxidative polymerization followed by carbonization and KOH activation. An easy and efficient vacuum-assisted impregnation followed by thermal treatment at a temperature of 350 degrees C is adopted to crystallize the SnO2 nanocrystals, realizing their embedment into the PG/CNW matrix. When evaluated for the electrochemical properties in lithium ion batteries, the obtained SnO2-PG/CNW composite exhibits a high lithium storage capacity of up to 1200 mA h g(-1), good cycling performance and outstanding rate capability. The preparation strategy is easy and efficient, providing a novel methodology for various types of heterogeneous nanocrystals embedded into porous matrix configuration for energy storage applications.