• 文献标题:   Asymmetric Supercapacitive Characteristics of PANI Embedded Holey Graphene Nanoribbons
  • 文献类型:   Article
  • 作  者:   GROVER S, GOEL S, SAHU V, SINGH G, SHARMA RK
  • 作者关键词:   polyaniline, graphene oxide nanoribbon, reduced graphene oxide nanoribbon, asymmetric supercapacitor, nanocomposite, in situ chemical polymerization
  • 出版物名称:   ACS SUSTAINABLE CHEMISTRY ENGINEERING
  • ISSN:   2168-0485
  • 通讯作者地址:   Univ Delhi
  • 被引频次:   32
  • DOI:   10.1021/acssuschemeng.5b00184
  • 出版年:   2015

▎ 摘  要

In the present study, graphene oxide nanoribbons (GONR) and reduced graphene oxide nanoribbons (RGONR) supported polyaniline (PANI) nanocomposites are synthesized via an in situ chemical polymerization method and investigated for super-capacitor electrodes. Electrochemical studies performed by cyclic voltammetry and galvanostatic charge-discharge (GCD) measurements suggest that both nanocomposites possess enhanced specific capacitance (C-sp as 740 F/g for GONR/PANI and 1180 F/g for RGONR/PANI at 5 mV/s). GONR/PANI and RGONR/PANI nanocomposites show good rate capability with high C-sp upon increasing the current density from 2 to 20 A/g in GCD measurements, approximately 55% decay in C-sp value of the nanocomposites is observed compared to pristine PANI (similar to 70%). The undertaken study signifies enhanced electrical and electrochemical properties of GONR/RGONR supported PANI nanocomposites due to a synergistic effect of GONR/RGONR and PANI. Furthermore, asymmetric devices are fabricated using GONR/RGONR as the negative electrode, while GONR/PANI and RGONR/PANI are used as the positive electrode, which exhibit significant enhancement in energy density and device performance.