• 文献标题:   Annealing free, clean graphene transfer using alternative polymer scaffolds
  • 文献类型:   Article
  • 作  者:   WOOD JD, DOIDGE GP, CARRION EA, KOEPKE JC, KAITZ JA, DATYE I, BEHNAM A, HEWAPARAKRAMA J, ARUIN B, CHEN YF, DONG H, HAASCH RT, LYDING JW, POP E
  • 作者关键词:   transfer, graphene, polymer, contaminant, chemical vapor deposition, layering
  • 出版物名称:   NANOTECHNOLOGY
  • ISSN:   0957-4484 EI 1361-6528
  • 通讯作者地址:   Univ Illinois
  • 被引频次:   58
  • DOI:   10.1088/0957-4484/26/5/055302
  • 出版年:   2015

▎ 摘  要

We examine the transfer of graphene grown by chemical vapor deposition (CVD) with polymer scaffolds of poly(methyl methacrylate) (PMMA), poly(lactic acid) (PLA), poly(phthalaldehyde) (PPA), and poly(bisphenol A carbonate) (PC). We find that optimally reactive PC scaffolds provide the cleanest graphene transfers without any annealing, after extensive comparison with optical microscopy, x-ray photoelectron spectroscopy, atomic force microscopy, and scanning tunneling microscopy. Comparatively, films transferred with PLA, PPA, PMMA/PC, and PMMA have a two-fold higher roughness and a five-fold higher chemical doping. Using PC scaffolds, we demonstrate the clean transfer of CVD multilayer graphene, fluorinated graphene, and hexagonal boron nitride. Our annealing free, PC transfers enable the use of atomically-clean nanomaterials in biomolecule encapsulation and flexible electronic applications.