• 文献标题:   Enhanced electrocatalytic activity of nitrogen-doped graphene for the reduction of nitro explosives
  • 文献类型:   Article
  • 作  者:   CHEN TW, XU JY, SHENG ZH, WANG K, WANG FB, LIANG TM, XIA XH
  • 作者关键词:   nitrogendoped grapheme, nitroaromatic compound, electrocatalysi, sensor
  • 出版物名称:   ELECTROCHEMISTRY COMMUNICATIONS
  • ISSN:   1388-2481 EI 1873-1902
  • 通讯作者地址:   Nanjing Univ
  • 被引频次:   29
  • DOI:   10.1016/j.elecom.2011.12.016
  • 出版年:   2012

▎ 摘  要

Nitrogen-doped graphene (NC) shows enhanced electrocatalytic activity toward the reduction of nitroaromatic compounds with a decreased overpotential (ca. 20 mV) compared with thermally reduced graphene (TR-G) and thus a NC-based sensing platform for sensitively electrochemical detection of TNT with a lower detection limit has been constructed. This prominent electrocatalytic activity of NC could be ascribed to the pyridine-like nitrogen atoms existing at the edge plane of graphene sheets. (C) 2011 Elsevier B.V. All rights reserved.