• 文献标题:   Activated graphene oxide/reduced graphene oxide electrodes and low viscous sulfonium cation based ionic liquid incorporated flexible gel polymer electrolyte for high rate supercapacitors
  • 文献类型:   Article
  • 作  者:   SULEMAN M, OTHMAN MAR, HASHMI SA, KUMAR Y, DERAMAN M, OMAR R, JASNI MRM
  • 作者关键词:   electricaldouble layer capacitor, activated graphene oxide, activated reduced graphene oxide, ionic liquid, plastic crystal, gel polymer electrolyte
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Univ Delhi
  • 被引频次:   10
  • DOI:   10.1016/j.jallcom.2016.12.023
  • 出版年:   2017

▎ 摘  要

High rate performance of symmetrical electrical-double layer capacitors (EDLCs) constructed with activated graphene oxide (ac-GO)/activated reduced graphene oxide (ac-RGO) electrodes and ionic liquid (triethylsulfonium bis(trifluoromethylsulfonyl) imide, incorporated plastic crystal succinonitrile (SN) based flexible gel polymer electrolytes (GPE) have been reported. The 3D architecture with predominantly meso-porous character of the ac-RGO, in combination with SN-based high ion conducting GPE, renders it a high rate electrode with high value of knee frequency, f(k) (similar to 966 Hz), low response time iota(0) (similar to 20 ms) and high pulse power P-0 (similar to 111 kW kg(-1)) as compared to the ac-GO-electrode that exhibits the corresponding values: fk (similar to 215 Hz), tau(0) (similar to 60 ms) and P-0 (similar to 58 kW kg(-1)). The ac-RGO based EDLCs offer higher specific power (similar to 118 kW kg(-1)) than that for ac-GO-based EDLC (similar to 41 kW kg(-1)), as evaluated from GCD studies. However, due to the additional pseudo-capacitance arising from leftover oxygen functional groups, the ac-GO-electrodes exhibit higher values of specific capacitance and specific energy (similar to 88 -96 F g(-1) and 25 Wh kg(-1), respectively) as compared to the ac-RGO based EDLCs with specific capacitance similar to 66-72 F g(-1) and specific energy similar to 18 Wh kg(-1)). Both the EDLC cells exhibit stable capacitive performance up to similar to 11,000-13,000 GCD cycles. (C) 2016 Elsevier B.V. All rights reserved.