• 文献标题:   Assessment on the mechanical, structural, and thermal attributes of green graphene-based water soluble polymer electrolyte composites
  • 文献类型:   Article
  • 作  者:   SULTANA S, BHATTI HN, YASMIN F, KHAN AN, REHAN I, REHAN K, NOORULAMIN
  • 作者关键词:   graphene oxide, mechanical, modified hummers method, morphological, poly ethylene oxide, sodium sulphate
  • 出版物名称:   JOURNAL OF APPLIED POLYMER SCIENCE
  • ISSN:   0021-8995 EI 1097-4628
  • 通讯作者地址:   Univ Peshawar
  • 被引频次:   1
  • DOI:   10.1002/app.48376 EA AUG 2019
  • 出版年:   2020

▎ 摘  要

In the current study, graphene oxide (GO) was prepared using green chemistry with modified Hummer's method without incorporating sodium nitrate (NaNO3). Solvent casting was employed to fabricate GO-doped poly(ethylene oxide) (PEO), that is, PEO/GO composites with various proportion of Na2SO4 and were then subjected to characterization via advanced spectroscopic techniques for different physicochemical aspects to estimate their potential applications as marketable products. XRD analysis explored that fabricated composites are more crystalline than neat PEO. PEO/GO/Na2SO4 composite films offered maximum crystallinity. SEM displayed the same trend. TG/DTA thermogram exposed better thermal stability than pristine polymer. FTIR studies confirmed complexation among hybrid's components. Elongation-at-break and Young's modulus displayed an enhancing behavior with an incremental loading of salt and filler. In terms of mechanical performance, composite of PEO with 0.37 wt % GO and 0.08 g salt was found to be an ideal composition during the course of study. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 48376.