• 文献标题:   Universal Transfer Printing of Micelle-Templated Nanoparticles Using Plasma-Functionalized Graphene
  • 文献类型:   Article
  • 作  者:   HUI LS, MUNIR M, VUONG A, HILKE M, WONG V, FANCHINI G, SCHARBER MC, SARICIFTCI NS, TURAK A
  • 作者关键词:   transfer printing, graphene, nanoparticle, perovskite, plasma etching, raman, photoluminescence
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244 EI 1944-8252
  • 通讯作者地址:   McMaster Univ
  • 被引频次:   0
  • DOI:   10.1021/acsami.0c12178
  • 出版年:   2020

▎ 摘  要

Nanostructure incorporation into devices plays a key role in improving performance, yet processes for preparing two-dimensional (2D) arrays of colloidal nanoparticles tend not to be universally applicable, particularly for soft and oxygen-sensitive substrates for organic and perovskite-based electronics. Here, we show a method of transferring reverse micelle-deposited (RMD nanoparticles (perovskite and metal oxide) on top of an organic layer, using a functionalized graphene carrier layer for transfer printing. As the technique can be applied universally to RMD nanoparticles, we used magnetic (gamma-Fe2O3) and luminescent (methylammonium lead bromide (MAPbBr(3))) nanoparticles to validate the transfer-printing methodology. The strong photoluminescence from the MAPbBr(3) under UV illumination and high intrinsic field of the gamma-Fe2O3 as measured by magnetic force microscopy (MFM), coupled with Raman measurements of the graphene layer, confirm that all components survive the transfer-printing process with little loss of properties. Such an approach to introducing uniform 2D arrays of nanoparticles onto sensitive substrates opens up new avenues to tune the device interfacial properties.