▎ 摘　　要

We create an interface of graphene with a metallic and magnetic support that leaves its electronic structure largely intact. This is achieved by exposing epitaxial graphene on ferromagnetic thin films of Co and Ni to vapor of the rare earth metal Eu at elevated temperatures, resulting in the intercalation of an Eu monolayer in between graphene and its substrate. The system is atomically well defined, with the Eu monolayer forming a (root 3x root 3)R30 degrees superstructure with respect to the graphene lattice. Thereby, we avoid the strong hybridization with the (Ni, Co) substrate 3d states that otherwise drastically modify the electronic structure of graphene. This picture is suggested by our x-ray absorption spectroscopy measurements which show that after Eu intercalation the empty 2p states of C atoms resemble more the ones measured for graphite in contrast to graphene directly bound to 3d ferromagnetic substrates. We use x-ray magnetic circular dichroism at the Co and Ni L-2,L-3 and Eu M-4,M-5 as an element-specific probe to investigate magnetism in these systems. An antiferromagnetic coupling between Eu and Co/Ni moments is found, which is so strong that a magnetic moment of the Eu layer can be detected at room temperature. Density functional theory calculations confirm the antiferromagnetic coupling and provide an atomic insight into the magnetic coupling mechanism.