▎ 摘　　要

Wearable mechanical energy harvesting technologies have been achieved much attention for the wireless sustainable power source applications. In this study, we have fabricated polyvinylidene fluoride (PVDF)/graphene quantum dot (GQD) composite nanofibers (NFs), which showed improved triboelectric nanogenerator (TENG) performance. PVDF/GQD composite NFs were fabricated by an electrospinning method. Structural and chemical investigations show that the GQDs were embedded in the PVDF NFs and promoted the formation of polar b-phase when an optimal amount of GQDs was incorporated. The PVDF/GQD NFs showed strong photoluminescence at a wavelength of 453 nm, which was attributed to the electronic transitions in the GQDs. As the GQD content increased from 0 to 5 vol%, the maximum output power from TENG devices increased from 35 to 97 mu W but decreased with further additions of GQDs. The enhancement and degradation of the TENG performance with increasing the GQD contents were due to the enhanced formation of polar beta-phase and the detrimental effect of conductive GQDs for charge trapping, respectively. (C) 2019 Elsevier B.V. All rights reserved.