• 文献标题:   Atomically-resolved edge states on surface-nanotemplated graphene explored at room temperature
  • 文献类型:   Article
  • 作  者:   MERINO P, SANTOS H, PINARDI AL, CHICO L, MARTINGAGO JA
  • 作者关键词:  
  • 出版物名称:   NANOSCALE
  • ISSN:   2040-3364 EI 2040-3372
  • 通讯作者地址:   INTA CSIC
  • 被引频次:   1
  • DOI:   10.1039/c7nr00367f
  • 出版年:   2017

▎ 摘  要

Graphene edges present localized electronic states strongly depending on their shape, size and border configuration. Chiral-or zigzag-ended graphene nanostructures develop spatially and spectrally localized edge states around the Fermi level; however, atomic scale investigations of such graphene terminations and their related electronic states are very challenging and many of their properties remain unexplored. Here we present a combined experimental and theoretical study on graphene stripes showing strong metallic edge states at room temperature. By means of scanning tunneling microscopy, we demonstrate the use of vicinal Pt(111) as a template for the growth of graphene stripes and characterize their electronic structure. We find the formation of a sublattice localized electronic state confined on the free-standing edges of the graphene ribbons at energies close to the Fermi level. These experimental results are reproduced and understood with tight-binding and ab initio calculations. Our results provide a new way of synthesizing wide graphene stripes with zigzag edge termination and open new prospects in the study of valley and spin phenomena at their interfaces.