• 文献标题:   One-Pot Synthesis of Carbon-Coated Nanostructured Iron Oxide on Few-Layer Graphene for Lithium-Ion Batteries
  • 文献类型:   Article
  • 作  者:   SUN ZY, MADEJ E, WIKTOR C, SINEV I, FISCHER RA, VAN TENDELOO G, MUHLER M, SCHUHMANN W, VENTOSA E
  • 作者关键词:   ferrocene, graphene, iron oxide, lithiumion batterie, nanostructure
  • 出版物名称:   CHEMISTRYA EUROPEAN JOURNAL
  • ISSN:   0947-6539 EI 1521-3765
  • 通讯作者地址:   Beijing Univ Chem Technol
  • 被引频次:   7
  • DOI:   10.1002/chem.201501935
  • 出版年:   2015

▎ 摘  要

Nanostructure engineering has been demonstrated to improve the electrochemical performance of iron oxide based electrodes in Li-ion batteries (LIBs). However, the synthesis of advanced functional materials often requires multiple steps. Herein, we present a facile one-pot synthesis of carbon-coated nanostructured iron oxide on few-layer graphene through high-pressure pyrolysis of ferrocene in the presence of pristine graphene. The ferrocene precursor supplies both iron and carbon to form the carbon-coated iron oxide, while the graphene acts as a high-surface-area anchor to achieve small metal oxide nanoparticles. When evaluated as a negative-electrode material for LIBs, our composite showed improved electrochemical performance compared to commercial iron oxide nanopowders, especially at fast charge/discharge rates.