• 文献标题:   One-step preparation of N-doped graphene/Co nanocomposite as an advanced oxygen reduction electrocatalyst
  • 文献类型:   Article
  • 作  者:   BAI F, HUANG H, TAN YL, HOU CM, ZHANG P
  • 作者关键词:   ndoped graphene, electrocatalyst, co nanocomposite, oxygen reduction reaction
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Jilin Univ
  • 被引频次:   20
  • DOI:   10.1016/j.electacta.2015.07.010
  • 出版年:   2015

▎ 摘  要

N-doped graphene/Co nanocomposites (NG/Co NPs) have been prepared by a simple one-step pyrolysis of Co(NO3)(2).6H(2)O, glucose and dicyandiamide (DCDA). The products with nitrogen doped and suitable graphitic degree perform high electrocatalytic activity (with the reduction peak at -0.099 V vs Ag/AgCl) and near four-electron selectivity for the oxygen reduction reaction (ORR), with excellent stability and durability in alkaline medium comparable to a commercial Pt/C catalyst. Owing to the superb ORR performance, low cost and facile preparation, the catalysts of NG/Co NPs have great potential applications in fuel cells, metal-air batteries and ORR-related electrochemical industries. (C) 2015 Elsevier Ltd. All rights reserved.