• 文献标题:   Cerium vanadate and reduced graphene oxide composites for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   WANG WL, JANG J, NGUYEN VH, AUXILIA FM, SONG H, JANG K, JIN EM, LEE GY, GU HB, HAM MH
  • 作者关键词:   cerium vanadate, reduced graphene oxide, composite, anode, lithiumion battery
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Gwangju Inst Sci Technol
  • 被引频次:   9
  • DOI:   10.1016/j.jallcom.2017.07.051
  • 出版年:   2017

▎ 摘  要

There has been a significant interest in the development of novel anode materials that can solve the problems of lithium plating and dendrite formation during the discharge-charge process, thus ensuring safety in Li-ion batteries. We synthesized tetragonal CeVO4 as an alternative to graphite, the active material in commercial Li-ion batteries, via a hydrothermal reaction; CeVO4 has lower lithium insertion potentials of 1.0 and 1.5 V versus Li+/Li compared to those of lithium titanium oxide. In order to overcome the drawbacks of the metal oxide, such as low electrical conductivity and volume change upon cycling, CeVO4/RGO composites were synthesized by mixing CeVO4 uniformly with reduced graphene oxide (RGO) via a solid-state reaction. The CeVO4/RGO composites exhibited improved cycling performance and rate capability, with relatively low charging potential of 1.35 V and high power density of 235 W g(-1) at 10 wt% RGO, as compared to the pure CeVO4. Our results suggest that the CeVO4/RGO composites have great potential for use as an anode in lithium ion batteries with high power density and excellent safety. (C) 2017 Elsevier B.V. All rights reserved.