• 文献标题:   Electrochemical fabrication of long-term stable Pt-loaded PEDOT/graphene composites for ethanol electrooxidation
  • 文献类型:   Article
  • 作  者:   JIANG FX, YAO ZQ, YUE RR, DU YK, XU JK, YANG P, WANG CY
  • 作者关键词:   graphene, poly 3 4ethylenedioxythiophene, pt nanoparticle, ethanol electrooxidation, electrocatalytic stability
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199
  • 通讯作者地址:   Soochow Univ
  • 被引频次:   47
  • DOI:   10.1016/j.ijhydene.2012.04.084
  • 出版年:   2012

▎ 摘  要

Layered electrochemically reduced graphene oxide (ER-GO) sheets incorporated with poly(3,4-ethylenedioxythiophene) (PEDOT) have been fabricated as an efficient support for Pt nanoparticles on a glassy carbon (GC) electrode. The as-prepared Pt-loaded PEDOT/ER-GO composite electrode exhibits not only the high mass peak current density (390 A g(-1)) but also the good long-term catalytic stability toward the ethanol electrooxidation. The Pt/PEDOT/ER-GO also shows stronger tolerance to poisoning species compared with the commercial JM 20% Pt/C electrode. The high electrocatalytic activity of Pt/PEDOT/ER-GO is mainly described to the good electrochemical activity of PEDOT/ER-GO composites and the well-dispersed Pt nanoparticles resulting in the large electrochemical active surface area of Pt (47.1 m(2) g(-1)). Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.