• 文献标题:   Excitonic effects in the optical spectra of graphene nanoribbons
  • 文献类型:   Article
  • 作  者:   YANG L, COHEN ML, LOUIE SG
  • 作者关键词:  
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984
  • 通讯作者地址:   Univ Calif Berkeley
  • 被引频次:   194
  • DOI:   10.1021/nl0716404
  • 出版年:   2007

▎ 摘  要

We present a first-principles calculation of the optical properties of armchair-edged graphene nanoribbons (AGNRs) with many-electron effects included. The reduced dimensionality of the AGNRs gives rise to an enhanced electron-hole binding energy for both bright and dark exciton states (0.8-1.4 eV for GNRs with width similar to 1.2 nm) and dramatically changes the optical spectra owing to a near complete transfer of oscillator strength to the exciton states from the continuum transitions. The characteristics of the excitons of the three distinct families of AGNRs are compared and discussed. The enhanced excitonic effects found here are expected to be of importance in optoelectronic applications of graphene-based nanostructures.