• 文献标题:   Sensitive Stripping Determination of Cadmium(II) and Lead(II) on Disposable Graphene Modified Screen-Printed Electrode
  • 文献类型:   Article
  • 作  者:   CHAO HF, FU L, LI YZ, LI XL, DU HJ, YE JS
  • 作者关键词:   graphene, screenprinted electrode, poly sodium 4styrenesulfonate, bismuth, stripping voltammetry
  • 出版物名称:   ELECTROANALYSIS
  • ISSN:   1040-0397 EI 1521-4109
  • 通讯作者地址:   S China Univ Technol
  • 被引频次:   22
  • DOI:   10.1002/elan.201300239
  • 出版年:   2013

▎ 摘  要

In the present work, a sensitive, facile and disposable sensing platform for trace analysis of heavy metal ions was developed at the Bi modified graphene-poly(sodium 4-styrenesulfonate) composite film screen printed electrode (GR/PSS/Bi/SPE). The GR/PSS/Bi/SPE improved sensitivity and linearity due to the functionalization of graphene with negatively charged PSS providing more absorbing sites. The detection limit of the GR/PSS/Bi/SPE is found to be 0.042 mu gL(-1) for Cd2+ and 0.089 mu gL(-1) for Pb2+ with linear responses of Cd2+ and Pb2+ in the range of 0.5-120 mu gL(-1). Finally, the practical application was confirmed in real water with satisfactory results.