• 文献标题:   Inducing metallicity in graphene nanoribbons via zero-mode superlattices
  • 文献类型:   Article
  • 作  者:   RIZZO DJ, VEBER G, JIANG JW, MCCURDY R, CAO T, BRONNER C, CHEN T, LOUIE SG, FISCHER FR, CROMMIE MF
  • 作者关键词:  
  • 出版物名称:   SCIENCE
  • ISSN:   0036-8075 EI 1095-9203
  • 通讯作者地址:   Univ Calif Berkeley
  • 被引频次:   0
  • DOI:   10.1126/science.aay3588
  • 出版年:   2020

▎ 摘  要

The design and fabrication of robust metallic states in graphene nanoribbons (GNRs) are challenging because lateral quantum confinement and many-electron interactions induce electronic band gaps when graphene is patterned at nanometer length scales. Recent developments in bottom-up synthesis have enabled the design and characterization of atomically precise GNRs, but strategies for realizing GNR metallicity have been elusive. Here we demonstrate a general technique for inducing metallicity in GNRs by inserting a symmetric superlattice of zero-energy modes into otherwise semiconducting GNRs. We verify the resulting metallicity using scanning tunneling spectroscopy as well as first-principles density-functional theory and tight-binding calculations. Our results reveal that the metallic bandwidth in GNRs can be tuned over a wide range by controlling the overlap of zero-mode wave functions through intentional sublattice symmetry breaking.