• 文献标题:   Preparation of metallic cobalt-graphene composites with enhanced electrochemical activity
  • 文献类型:   Article
  • 作  者:   WANG L, WANG DL, HU XC, ZHU JS, LIANG XS
  • 作者关键词:   metallic cobalt, cobalt hydroxide, graphene, hydrothermal reaction, supercapacitor
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686
  • 通讯作者地址:   Harbin Inst Technol
  • 被引频次:   15
  • DOI:   10.1016/j.electacta.2012.05.022
  • 出版年:   2012

▎ 摘  要

Metallic cobalt-graphene composites were synthesized through coprecipitation synthetic method followed by hydrothermal treatment at 180 degrees C. The composite material as prepared was characterized using X-ray diffraction (XRD), SEM, TEM, Energy dispersive spectrometer (EDS) analysis and Thermogravimetric (TG) analysis. The results indicate that metallic cobalt particles possess a good dispersion on the surface of graphene. The electrochemical performance of metallic cobalt-graphene composites was characterized by Cyclic voltammetry (CV) and galvanostatic charge-discharge tests. The specific capacitance of the composite material approaches 1340 Fg(-1) at current density of 1.5 A g(-1) with a capacitance retention rate of 82% at current density of 3.5 A g(-1). The results suggest that the combination of metallic cobalt and graphene leads to synergistic performance, which inherits the overall system with enhanced electrochemical performance. (C) 2012 Elsevier Ltd. All rights reserved.