• 文献标题:   Adsorption of sodium diclofenac in aqueous medium using graphene oxide nanosheets
  • 文献类型:   Article, Early Access
  • 作  者:   GUERRA ACS, DE ANDRADE MB, DOS SANTOS TRT, BERGAMASCO R
  • 作者关键词:   adsorption, pharmaceutical, graphene oxide, sodium diclofenac, water treatment
  • 出版物名称:   ENVIRONMENTAL TECHNOLOGY
  • ISSN:   0959-3330 EI 1479-487X
  • 通讯作者地址:   Univ Estadual Maringa
  • 被引频次:   1
  • DOI:   10.1080/09593330.2019.1707882 EA DEC 2019
  • 出版年:  

▎ 摘  要

In this work, the adsorption of sodium diclofenac (DCF) on graphene oxide nanosheets (GON) was evaluated. GON was synthesized by the modified Hummers method and characterized regarding its composition, morphology, and surface load. It was applied in batch adsorption tests. The process was evaluated from the kinetic, isothermal and thermodynamic properties, and parameters such as adsorbent mass and solution pH were optimized. The best working condition was observed at the natural pH of the solution (6.2) and 0.25 g L-1 adsorbent dosage. The pseudo-first-order and pseudo-second-order models were applied to verify the behaviour of the adsorption kinetics, and the adsorption isotherms were also developed at temperatures ranging from 25 degrees C to 45 degrees C. The isotherm models of Langmuir, Freundlich, and Temkim were applied to the equilibrium data. The thermodynamic parameters of enthalpy, entropy, and Gibbs free energy were evaluated to describe the behaviour of the adsorptive process. The maximum adsorption capacity of DCF at 25 degrees C was 128.74 mg g(-1) with a removal rate of 74% in 300 min. The process was favourable and spontaneous with adsorptive capacity decreasing with increasing temperature. In addition, an adsorption mechanism was proposed to show the possible bonds that occur between adsorbate and adsorbent and the interactions formed through the influence of pH.