• 文献标题:   Facile growth of centimeter-sized single-crystal graphene on copper foil at atmospheric pressure
  • 文献类型:   Article
  • 作  者:   LI J, WANG XY, LIU XR, JIN Z, WANG D, WAN LJ
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY C
  • ISSN:   2050-7526 EI 2050-7534
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   52
  • DOI:   10.1039/c5tc00235d
  • 出版年:   2015

▎ 摘  要

By mildly oxidizing Cu foil and slowing down the total gas flow rate, we develop an easily repeatable atmospheric growth method to grow single-crystal graphene of centimeter-size. The graphene edge, which is different from the previously reported straight edge, is connected by a series of graphene-corners. The graphene-corner, ranging between 100 degrees and 110 degrees, is formed by a zig-zag edge and a mix edge. The oxidation of Cu crystal boundaries results in the rearrangement of active Cu sites for graphene nucleation, thus suppressing graphene nucleation density.