▎ 摘　　要

Hard carbon has emerged as a candidate for anode material because of its abundant resources and large interlayer spacing for lithium/sodium storage. However, disordered amorphous carbon with low electronic conductivity and poor stability restricts its valuable application. Herein, this work demonstrates a design of honeycomb-like porous carbon with nanographitic domains, supported on graphene layers. The highly ordered graphene layer constructs a conductive network for high-speed electronic transport throughout the entire structure. The honeycomb-like amorphous structure with nanopores favors the interfacial storage of lithium/sodium ions, enabling high reversible capacity. More importantly, the introduction of nanographitic domains into carbon matrix is an effective method for improving electronic transport and stabilizing reversible ion insertion/desertion because of expanded interlayer distance (0.36 nm). When serving as anode material for lithium storage, it exhibits a stable capacity of 1390.1 mA h g(-1) at the current density of 0.2 A g(-1), with excellent cycling stability (721.4 mA h g(-1) after 200 cycles at a 1.0 A g(-1)) and even remains at 202.8 mA h g(-1) undergoing 5000 cycles at 10 A g(-1). Furthermore, a high reversible sodium storage capacity of 352.1 mA h g(-1) is obtained, also with good stability of 124.4 mA h g(-1) after 500 cycles at 1.0 A g(-1). We believe that the material is promising for lithium/sodium storage with excellent performance.