• 文献标题:   Precipitation synthesis and enhanced electrochemical performance of graphene-modified LiMn(2)O(4)for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   LI AX, SHAO ZC, YANG SH, LI XT, ZHANG AL
  • 作者关键词:   limn2o4, lithium ion batterie, graphene, performance
  • 出版物名称:   IONICS
  • ISSN:   0947-7047 EI 1862-0760
  • 通讯作者地址:   Shenyang Ligong Univ
  • 被引频次:   1
  • DOI:   10.1007/s11581-019-03432-4
  • 出版年:   2020

▎ 摘  要

The graphene-modified LiMn(2)O(4)cathode material was synthesized by precipitation method. X-ray diffraction (XRD), scanning electron microscopy (SEM), and fourier transform infrared (FITR) showed LiMn(2)O(4)had been successfully combined with the graphene. The charge and discharge tests and electrochemical impedance spectroscopy (EIS) were used to study electrochemical properties of as-synthesized material. The results showed that the electrochemical properties of the graphene oxide-supported LiMn(2)O(4)were superior to that of the LiMn(2)O(4)material. The initial discharge capacity of the graphene-modified LiMn(2)O(4)material reached 127 mAh g(-1). After 100 cycles, it still had a capacity retention rate of 96.2%. Enhanced electrochemical performance of graphene-supported LiMn(2)O(4)could be attributed to the establishment of fast Li(+)channels and structural stability after coating LiMn(2)O(4)with the graphene.