• 文献标题:   Anchoring ZnO Nanoparticles in Nitrogen-Doped Graphene Sheets as a High-Performance Anode Material for Lithium-Ion Batteries
  • 文献类型:   Article
  • 作  者:   YUAN GH, XIANG JM, JIN HF, WU LZ, JIN YZ, ZHAO Y
  • 作者关键词:   anode material, graphene nanocomposite, lithiumion battery, zno/nitrogendoped, zno nanoparticle
  • 出版物名称:   MATERIALS
  • ISSN:   1996-1944
  • 通讯作者地址:   GDUT
  • 被引频次:   10
  • DOI:   10.3390/ma11010096
  • 出版年:   2018

▎ 摘  要

A novel binary nanocomposite, ZnO/nitrogen-doped graphene (ZnO/NG), is synthesized via a facile solution method. In this prepared ZnO/NG composite, highly-crystalline ZnO nanoparticles with a size of about 10 nm are anchored uniformly on the N-doped graphene nanosheets. Electrochemical properties of the ZnO/NG composite as anode materials are systematically investigated in lithium-ion batteries. Specifically, the ZnO/NG composite can maintain the reversible specific discharge capacity at 870 mAh g(-1) after 200 cycles at 100 mA g(-1). Besides the enhanced electronic conductivity provided by interlaced N-doped graphene nanosheets, the excellent lithium storage properties of the ZnO/NG composite can be due to nanosized structure of ZnO particles, shortening the Li+ diffusion distance, increasing reaction sites, and buffering the ZnO volume change during the charge/discharge process.