• 文献标题:   Enzyme-directed pH-responsive exfoliation and dispersion of graphene and its decoration by gold nanoparticles for use as a hybrid catalyst
  • 文献类型:   Article
  • 作  者:   QU KG, WU L, REN JS, QU XG
  • 作者关键词:   grapheme, exfoliation, lysozyme, phresponsive, catalysi, protein
  • 出版物名称:   NANO RESEARCH
  • ISSN:   1998-0124
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   12
  • DOI:   10.1007/s12274-013-0345-3
  • 出版年:   2013

▎ 摘  要

A non-destructive, safe and practical strategy to produce high quality graphene in high yield is urgently required, since this would pave the way for a wide range of applications of graphene in the future. Here we present a pH-responsive water-dispersible method for the exfoliation and functionalization of graphene by using lysozyme. The pH-responsive dispersion of graphene may be useful for the reversible assembly of multicomponent/multifunctional nanohybrid materials and nanoscale electronic devices. More importantly, composites can be easily constructed through the interactions between disulphide groups in lysozyme and gold nanoparticles (AuNPs). The resulting graphene-AuNPs composites show excellent catalytic activity towards reduction of o-nitroaniline by NaBH4. Since lysozyme is low cost and has antibacterial properties, and has been widely used in food preservation, medicine and the pharmaceutical industry, our approach may open a new scalable route for the manufacture of high-quality, nondestructive graphene for practical applications.