• 文献标题:   Thermal stability of graphene in inert atmosphere at high temperature
  • 文献类型:   Article
  • 作  者:   LIU F, WANG MJ, CHEN Y, GAO JM
  • 作者关键词:   graphene, inert atmosphere, high temperature, stability, defect
  • 出版物名称:   JOURNAL OF SOLID STATE CHEMISTRY
  • ISSN:   0022-4596 EI 1095-726X
  • 通讯作者地址:   Beijing Forestry Univ
  • 被引频次:   6
  • DOI:   10.1016/j.jssc.2019.04.008
  • 出版年:   2019

▎ 摘  要

To investigate the thermal stability of graphene during sintering process of ceramic, the effect of temperature on stability of single-layer graphene (SLG) in argon atmosphere was studied. The Raman D-band/G-band intensity ratio(I-D/I-G) and the blue shifts of G mode showed that, the graphene defect density gradually increased with the increase in heat treatment temperature (HTT). There was limited damage in the graphene when treated temperature lower than 800 degrees C. The causes of the defects were discussed. The defect types were mainly on-set defects. Boundary defects were detected when the temperature reached above 800 degrees C. Atom Force Microscope (AFM) results showed that the defects gradually extended from the boundary and holes in the layer to the edge and ultimately led to isolated graphene islands. The experiment results could be useful to study the changes and developing the holistic performance of graphene in high temperature sintering process.