• 文献标题:   Electrochemical performance of honeycomb graphene prepared from acidic graphene oxide via a chemical expansion method
  • 文献类型:   Article
  • 作  者:   FU HY, GAO B, LIU Z, LIU WT, WANG ZZ, WANG M, LI JH, FENG ZB, KAMALI AR
  • 作者关键词:   chemically expanded graphene, nanocrystalline graphene, specific capacity
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1016/j.jelechem.2022.116545 EA JUL 2022
  • 出版年:   2022

▎ 摘  要

High-performance electrode materials are particularly important for the next-generation of supercapacitors with enhanced specific capacity and cycle stability. In this study, a simple and scalable thermal expansion method is used to convert acidic graphite oxide (AGO) into chemically expanded graphene (CEG) nanostructure, with a honeycomb morphology consisting of 2-3 graphene layers. The CEG produced by the thermal expansion of AGO under modified conditions of time and duration (CEG-2) exhibits a substantially large specific surface area of around 388 m(2).g(-1), in comparison to value of 6 m(2).g(-1) recorded on the virgin superconducting graphite powder. This provides the CEG-2 material with an excellent specific capacitance of 283.8F.g(-1), recoded at 1 A.g(-1). The cycle stability of CEG-2 is characterized to be highly desirable with a retention rate of around 87% after 5000 cycles. The results obtained suggest the enhanced electrochemical performance of CEG.