• 文献标题:   Preparation of crumpled reduced graphene oxide-poly(p-phenylenediamine) hybrids for the detection of dopamine
  • 文献类型:   Article
  • 作  者:   LIU S, YU B, ZHANG T
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Jilin Univ
  • 被引频次:   42
  • DOI:   10.1039/c3ta12594g
  • 出版年:   2013

▎ 摘  要

In this work, reduced graphene oxide-poly(p-phenylenediamine) (rGO-PpPD) hybrids have been successfully prepared through a facile and effective method by heat treatment of GO aqueous dispersion in the presence of pPD at 80 degrees C for 2 h. The combined characterization by scanning electron microscopy (SEM), transmission electron microscopy (TEM), infrared (FT-IR) spectroscopy and X-ray photoelectron spectroscopy (XPS) indicates the successful production of rGO-PpPD hybrids with a crumpled morphology. The formation of rGO-PpPD hybrids is attributed to the redox reactions between GO and pPD, where the reduction of GO to rGO and polymerization of pPD into PpPD occurred simultaneously. It was found that rGO-PpPD hybrids show good catalytic activity toward oxidation of dopamine (DA), and no response to ascorbic acid (AA) and uric acid (UA), leading to a high-performance DA sensor. The linear detection ranges are estimated to be from 5 mu M to 25 mu M (r = 0.998) and 50 mu M to 200 mu M (r = 0.995), respectively. The detection limit is estimated to be 0.36 mu M at a signal-to-noise ratio of 3.